Setup your VPN using the HOWTO:
HOWTO: For OpenVPN Community Edition
(Recommend reading all of it)
Once you have a working VPN Implement this HOWTO(2):
HOWTO: Routing all client traffic (including web-traffic) through the VPN
You can try
NATHack on the
server. (Or you can learn routing)
Also, ensure
IP forwarding is enabled on your server .. And your
client.
Once you have done all that you can use iptables NAT on your
client (not server)
similar to the way it is shown in that HOWTO(2)
(When you get to this stage we can work out the iptables rule you will need)
It is complicated, so don't expect it to work straight away .. and I may have forgotten / overlooked something.