Technically, we do not support router devices .. however ..
pmatil wroteThere is a firewall / dhcp server at address 192.168.0.1 / 255.255.255.0
This is the number one worse subnet you can choose ..
You are strongly recommended to find a way to change it to a more unique subnet.
Unique example: 192.168.159.0/24
pmatil wrotebut I cannot access any other device except the router itself, which is at address 10.10.0.1
Well, it is a good start .. but you are going to need to read some docs on this.
pmatil wroteSo .100 becomes .1. Can this even work?
does not "become" but has two ip addresses.
pmatil wroteI cannot figure out how the other devices map into the VPN address range
You need to read our documentation and that of your router and probably openWRT.
pmatil wroteThe connecting client gets ip address 10.10.0.6.
That is good ..
Please read our entire howto:
https://openvpn.net/index.php/open-source/documentation/howto.html