nice to see that you reposted in english... :mrgreen:
What I wonder is:
01 - How to make the machines on the network "A" find the network of "B" (because the hosts are located and machinery).
02 - I need all machines are clients of VPN for this to occur?
03 - OpenVPN needs to be my gateway for this to happen or he can stay behind another gatway?
your problem is routing...
you need:
set up a static route to each one of your pcs for the remote network pointing to your openvpn server/client lan
or
go to your pcs default gateway and add the static route there....
also you MUST have ip forwarding enabled on both openvpn server/client,
btw which centos are you using?
Michael.