this happens because you're not redirecting all traffic via the OpenVPN server; in principle this can be done on the VPN server by adding a line
push "redirect-gateway def1"
but you will need to take some additional steps to get it working on your Win7 desktop : what is needed is IP forwarding and some type of Network Address Translation; if you're lucky then you can add a route on your home router to accept (and foward) VPN traffic - if not, then you'll have to set up NATting on Win7, which is doable but not nice.