you will need to export the PKCS7 (p7b) file to something that openvpn understands, OR you can use the 'cryptoapi' option to query the Windows CryptoAPI store directly. You will always need to export the CA certificate as a pem file, however.
To print all certficiates in a pkcs7 file, use
openssl pkcs7 -in file.pem -print_certs -out certs.pem